Geochemical Assessment Methods of Outcropped Metasedimentary/Metamorphic and Deeply Buried Sedimentary Oil and Gas Source Rocks by Hydrocarbon-Rich Waters and Soils: A Novel Graphical Approach and Case Studies

  • Adil Özdemir Aydeniz Consulting Co. Ltd.
  • Yildiray Palabiyik Istanbul Technical University
Keywords: Metamorphosed source rock, Buried source rock, Hydrocarbon-rich water, Hydrocarbon-rich soil, TPH in water analysis, TPH in soil analysis

Abstract

This study presents the applied methods used for geochemical evaluation of metasedimentary/metamorphic (depleted/exhausted/spent source rocks) and deeply buried sedimentary source rocks from hydrocarbon-rich waters and soils. Someone can determine all parameters used in geochemical assessments of source rocks by conducting TPH (Total Petroleum Hydrocarbons) analysis in both water and soil. It is considered that our knowledge about the metamorphosed source rocks will increase as the applications of methods discussed in this chapter increase. Within the study's scope, the Pr/n-C17 versus Ph/n-C18 plot used to evaluate the source, depositional environment, redox conditions of the depositional environment, thermal maturity, and hydrocarbon generation potential of source rocks in petroleum geochemistry is also comprehensively revised. In the revised plot, the ranges for API gravity, specific gravity (SG), sulfur content (S), biodegradation parameter (BP), vitrinite reflectance (Ro%), and maximum temperature (Tmax) values are defined. Thus, a new approach is developed to estimate API gravities and sulfur contents of petroleum fluids that might be discovered within reservoirs in any specified prospective area from surface geochemical surveys. Furthermore, humic and sapropelic coal ranges are separated. In this way, the plots' functionality and efficiency are developed, making petroleum geochemical assessments possible in only one diagram instead of using several graphs or charts.

References

Abboud M, Philp RP, Allen J et al (2005) Geochemical correlation of oils and source rocks from central and NE Syria. Journal of Petroleum Geology 28(2):203-216
Abdullah WA (1999) Organic facies variations in the Triassic shallow marine and deep marine shales of central Spitsbergen, Svalbard. Marine and Petroleum Geology 16:467-481
Adepojua A, Adekolaa SA, Omotoyea S et al (2018) Light hydrocarbon geochemistry of crude oils from Eastern Niger Delta. Petroleum Science and Technology, 36(19):1573-1581
Ader M, Cartigny P, Boudou J et al (2006) Nitrogen isotopic evolution of carbonaceous matter during metamorphism: Methodology and preliminary results. Chemical Geology 232:152-169
Ahmed W, Alam S, Jahandad S (2004) Techniques and methods of organic geochemistry as applied to petroleum exploration. Pakistan Journal of Hydrocarbon Research 14:69-77
Aldahik A (2010) Crude Oil Families in the Euphrates Graben Petroleum System. PhD Thesis, Berlin Institute of Technology
Alexander R, Kagi R, Woodhouse GW (1981) Geochemical correlation of Windalia oil and extracts of Winning Group (Cretaceous) potential source rocks, Barrow Subbasin, Western Australia. AAPG Bulletin 65:235-250
Alexander G, Hazai I (1981) Chromatographic fingerprinting of coal extracts. Journal of Chromatography 217:19-38
Amijaya DH (2005) Paleoenvironmental, paleoecological and thermal metamorphism implications on the organic petrography and organic geochemistry of Tertiary Tanjung Enim coal, South Sumatra Basin, Indonesia. PhD Thesis, Aachen University
Anyigba LK, (2021) Prediction of API Gravity (Oil Quality) Using Some Geochemical Parameters with Ensemble Boosted Trees and Smoothing Spline Correlation Models. MSc Thesis, Istanbul Technical University
Asif M, Grice K, Fazeelat T (2009) Assessment of petroleum biodegradation using stable hydrogen isotopes of individual saturated hydrocarbon and polycyclic aromatic hydrocarbon distributions in oils from the Upper Indus Basin, Pakistan. Organic Geochemistry 40:301-311
Azhar HM (2012) Petroleum Geochemistry of the So-Called “Dry Wells” Off Mid-Norway. MSc Thesis, University of Oslo
Azmy K, Kendall B, Creaser RA et al (2008) Global correlation of the Vazante Group, São Francisco Basin, Brazil: Re-Os and U-Pb radiometric age constraints. Precamb Res 164:160-172
Baioumy HM, Eglinton LB, Peucker-Ehrenbrink B (2011) Rhenium–osmium isotope and platinum group element systematics of marine vs. non-marine organic-rich sediments and coals from Egypt. Chemical Geology 285:70-81
Barker C (1979) Organic Geochemistry in Petroleum Explo¬ration. AAPG Continuing Education Course Note Series 10, p 159
Bechtel A, Gruber W, Sachsenhofer RF et al (2001) Organic geochemical and stable isotopic investigation of coals formed in low-lying and raised mires within the Eastern Alps (Austria). Organic Geochemistry, 32:1289-1310
Beyer J, Jonsson G, Porte C et al (2010) Analytical methods for determining metabolites of polycyclic aromatic hydrocarbon (PAH) pollutants in fish bile: a review. Environ Toxicol Pharmacol 30(3):224-244
Bostick NH (1979) Microscopic measurement of the level of catagenesis of solid organic matter in sedimentary rocks to aid exploration for petroleum and to determine former burial temperatures - A review. Society of Economic paleontologists and Mineralogists Special Publication 26:17-43
Böcker J, Littke R, Forster A (2017) An overview on source rocks and the petroleum system of the central Upper Rhine Graben. International Journal of Earth Science (Geol Rundsch), 106:707-742
Bray EE, Evans ED (1961) Distribution of n-paraffins as a clue to recognition of source rocks. Geochim Cosmochim Acta 22:2-15
Chaffee A, Hoover D, Johns R et al (1986) Biological markers extractable from coal. In: John R (ed) Biological Markers in the Sedimentary Record, Elsevier, p 311-345
Chakhmakhchev A, Suzuki M, Takayama K (1997) Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments. Organic Geochemistry 26(7-8):483-489
Chandra K, Mishra CS, Samanta U et al (1994) Correlation of different maturity parameters in the Ahmedabad - Mehsana block of the Cambay basin. Organic Geochemistry 21:313-321
Chang X, Wang T, Li Q et al (2012) Maturity assessment of severely biodegraded marine oils from the Halahatang Depression in Tarim Basin. Energy Exploration and Exploitation 30(3):331-350
Cohen AS, Coe AL, Bartlett JM et al (1999) Precise Re-Os ages of organic-rich mudrocks and the Os isotope composition of Jurassic seawater. Earth Planet Sci Lett 167:159-173
Cohen AS (2004) The rhenium-osmium isotope system: applications to geochronological and palaeoenvironmental problems. Journal of the Geological Society London 161:729-734
Connan J (1981) Biological markers in crude oils. In: Mason JF (ed) Petroleum Geology in China, Penn Well, Tulsa, OK, p 48-70
Connan J (1984) Biodegradation of crude oils in reservoirs. In: Brooks J, Welte DH (eds.) Advances in Petroleum Geochemistry, vol. 1. Academic Press, London, p 299-335
Connan J, Cassou AM (1980) Properties of gases and petroleum liquids derived from terrestrial kerogen at various maturation levels. Geochim Cosmochim Acta 44(1):1-23
Creaser RA, Sannigrahi P, Chacko T et al (2002) Further evaluation of the ReOs geochronometer in organic-rich sedimentary rocks: a test of hydrocarbon maturation effects in the Exshaw Formation Western Canada Sedimentary Basin. Geochim Cosmochim Acta 66:3441-3452
Cumming VM, Selby D, Lillis PG (2012) Re-Os geochronology of the lacustrine Green River Formation: Insights into direct depositional dating of lacustrine successions, Re-Os systematics and paleocontinental weathering. Earth and Planetary Science Letters 359-360:194-205
Cumming VM (2013) Rhenium-osmium geochronology and geochemistry of ancient lacustrine sedimentary and petroleum systems. Durham theses, Durham University. Available at Durham E-Thesis Oline: http://ethesis.dur.ac.uk/6945
Cumming VM, Selby D, Lillis PG et al (2014) Re-Os geochronology and Os isotope fingerprinting of petroleum sourced from a Type I lacustrine kerogen: Insights from the natural Green River petroleum system in the Uinta Basin and hydrous pyrolysis experiments. Geochim Cosmochim Acta 138:32-56
de Abreu CR, de Souza ES, Martins LL et al (2020) Application of the electron spin resonance technique in the characterization of Brazilian oils: Correlation with their biodegradation level and polar composition. Energy & Fuels. https://dx.doi.org/10.1021/acs.energyfuels.0c02624
Didyk BM, Simoneit BRT, Brassel SC et al (1978) Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature 272:216-222
Dow WG (1977) Petroleum Source Beds on Continental Slopes and Rises. AAPG Continuing Education Course Notes Series 5, p D1-D37
Dzou LIP, Hughes WB (1993) Geochemistry of oils and condensates, K Field, offshore Taiwan: a case study in migration fractionation. Organic Geochemistry 20:427-462
Dultsev FF, Chernykh AV (2020) Geochemistry of water-dissolved gases of oil-and-gas bearing deposits in Northern and Arctic Regions of Western Siberia. IOP Conf. Series: Earth and Environmental Science. https://doi.org/10.1088/1755-1315/459/4/042024
Dumitru M, Vladimirescu A (2017) Loads limits values of soils with petroleum hydrocarbons. Geophysical Research Abstracts, 19, EGU2017-12351
El Diasty WS, El Beialy SY, Peters KE et al (2018) Organic geochemistry of the Middle-Upper Jurassic Naokelekan Formation in the Ajil and Balad oil fields, northern Iraq. Journal of Petroleum Science and Engineering 2018:350-362
El Diasty W Sh, El Beialy SY, Mahdi AQ et al (2016) Geochemical characterization of source rocks and oils from northern Iraq: Insights from biomarker and stable carbon isotope investigations. Marine and Petroleum Geology 77:1140-1162
Erstad K, Hvidsten IV, Askvik KM et al (2009) Changes in crude oil composition during laboratory biodegradation: Acids and oil-water, oil-hydrate interfacial properties. Energy & Fuel 23:4068-4076
Eymold WK, Swana K, Moore MT et al (2018) Hydrocarbon-rich groundwater above shale-gas formations: A Karoo basin case study. Groundwater 56(2):204-224
Finlay AJ, Selby D, Gröckea DR (2010) Tracking the Hirnantian glaciation using Os isotopes. Earth Planet Sci Lett 293:339-348
Finlay AJ, Selby D, Osborne MJ (2011) Re-Os geochronology and fingerprinting of United Kingdom Atlantic margin oil: Temporal implications for regional petroleum systems. Geology 39:475-478
Fu J, Guoying S, Xu J et al (1990) Application of biological markers in the assessment of paleoenvironments of Chinese non-marine sediments. Organic Geochemistry 16:769-779
Georgiev S, Stein HJ, Hannah JL et al (2011) Hot acidic Late Permian seas stifle life in record time. Earth Planet Sci Lett 310:389-400
Georgiev S, Stein HJ, Hannah JL et al (2012) Chemical signals for oxidative weathering predict Re‐Os isochroneity in black shales, East Greenland. Chemical Geology 324‐325:108‐121
Ghasemlounia R, Ozdemir A, Palabiyik Y et al (2020) Investigation of Hydrocarbon Contamination of Surface and Subsurface Waters in the West-Northwest Konya Province with TPH (Total Petroleum Hydrocarbons) in Water Analysis. İstanbul Gedik University, Scientific Research Project ID: GDK202006-03 (Ongoing project)
Gomez, K.J., 2016. Application of Biomarker Data in Oil Characterization. MSc Thesis, Technical University of Crete
Goossens H, de Leeuw JW, Schenck PA et al (1984) Tocopherols as likely precursors of pristane in ancient sediments and crude oils. Nature 312:440-442
Hakimi HM, Alaug A, Afify WE, El Nady MM et al (2019) Investigating gas resource potentiality from Late Jurassic Madbi Formation in the NW -Say’un-Masila Basin, Eastern Yemen. Petroleum Science and Technology 37(12): 1355-1362,
Hakimi HM, El Nady MM, Mohyaldin I et al (2018a). Thermal modeling and hydrocarbon generation of the Late Jurassic-Early Cretaceous Chia Gara Formation in Iraqi Kurdistan region, northern Zagros Fold Belt. Egyptian Journal of Petroleum 27(4): 701-413
Hakimi HM, Alaug A, Ahmed AF et al (2018b). Simulation the timing of petroleum generation and expulsion from deltaic source rocks: Implications for Late Cretaceous petroleum system in the offshore Jiza-Qama, Eastern Yemen. Journal of Petroleum Science and Engineering 170: 620-642, doi.org/10.1016/j.petrol.2018.06.076
Hannah JL, Stein HJ, Xu G et al (2014) Age and composition of source rocks: new steps toward tracking hydrocarbon migration. Paper presented at International Petroleum Technology Conference (IPTC), Doha, Qatar, 20‐22 January 2014
Hartkopf-Fröder C, Kloppisch M, Mann U et al (2007) The end-Frasnian mass extinction in the Eifel Mountains, Germany: New insights from organic matter composition and preservation. Geol Soc London Special Public 278:173-196
Harris NB, Mnich CA, Selby D et al (2013) Minor and trace element and Re-Os chemistry of the Upper Devonian Woodford Shale, Permian Basin, west Texas: Insights into metal abundance and basin processes. Chemical Geology 356:76-93
Havelcová M, Sy´korová I, Trejtnarová H et al (2012) Identification of organic matter in lignite samples from basins in the Czech Republic: Geochemical and petrographic properties in relation to lithotype. Fuel 99:129-142
Head IM, Jones DM, Larter SR (2003) Biological activity in the deep subsurface and the origin of heavy oil. Nature 426:344-352
Heroux Y, Chagnon AG, Bertrand R (1979) Compilation and correlation of major thermal maturation indicators. AAPG Bulletin 63:2128-2144
Hu J, Zhang X, Yu Q et al (2014) Viscosity prediction of heavy oil from the Liaohe Basin using biomarker parameters. Petroleum Science and Technology 32:1028-1037
Hu S, Evans K, Craw D et al (2015) Raman characterization of carbonaceous material in the Macraes orogenic gold deposit and metasedimentary host rocks, New Zealand. Ore Geology Reviews 70:80-95
Hughes WB, Holba AG, Dzou LIP (1995) The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks. Geochim Cosmochim Acta 59(17):3581-3598
Hunt JM (1979) Petroleum Geochemistry and Geology. In: Gilluly J (ed) WH Freeman and Company, San Francisco
Hunt JM (1996) Petroleum Geochemistry and Geology. WH Freeman. New York
Hunt JM (1996) Petroleum Geochemistry and Geology. Second edn. WH Freeman, New York
Ishiwatari R, Ishiwatari RM (2004) Insights on the origin of pristane and phytane in sediments and oils from laboratory heating experiments. In: Isaac R, Kaplan RJ, Hill J et al (eds.) Geochemical Investigations in Earth and Space Science: A Tribute. The Geochemical Society 9:85-96
Ishiwatari R, Ishiwatari M, Rohrback GB et al (1977) Thermal alteration experiments on organic matter from recent marine sediments in relation to petroleum genesis. Geochim Cosmochim Acta 41:815-828
ISO 5667-3 (2018) Water quality - Sampling - Part 3: Preservation and handling of water samples
ISO 9377-2 (2000) Water quality - Determination of hydrocarbon oil index - Part 2: Method using solvent extraction and gas chromatography
ISO 16703 (2011) Soil quality - Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography
ISO 14039 (2005) Characterization of waste - Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography
ISO 10381-1 (2002) Soil quality - Sampling - Part 1: Guidance on the design of sampling programmes
ISO 10381-2 (2002) Soil quality - Sampling - Part 2: Guidance on sampling techniques
ISO 18400 (2018) Soil quality - Sampling
Judik K, Rantitsch G, Rainer TM et al (2008) Alpine Metamorphism of organic matter in metasedimentary rocks from Mt. Medvednica (croatia). Swiss J. Geosci. https://doi.org./10.1007/s00015-008-1303-z
Kara-Gülbay R, Yaylalı-Abanuz G, Korkmaz S et al (2019) Organic matter type, maturity, depositional environmental characteristics, and liquid hydrocarbon potential of Late Carboniferous Kozlu Bituminous Coal and Coaly Shale Beds (Zonguldak-Amasra Basin, NW Anatolia, Turkey): An application of biomarker geochemistry. Energy & Fuels 33:9491-9509
Kato S, Waseda A, Nishita H (2006) Geochemical characteristics of crude oils from the Sagara oil field, Shizuoka Prefecture, Japan. Island Arc 15:304-312
Kayukova GP, Mikhailova AN, Kosachev ANI et al (2020) The oil-bearing strata of Permian deposits of the Ashal’cha Oil Field depending on the content, composition, and thermal effects of organic matter oxidation in the rocks. Geofluids. https://doi.org/10.1155/2020/6304547
Kendall B, Creaser RA, Selby D (2009) 187Re/188Os geochronology of Precambrian organic-rich sedimentary rocks. Geol Soc London Special Public 326:85-107
Kendall BS, Creaser RA, Ross GM et al (2004) Constraints on the timing of Marinoan 681 ‘Snowball Earth’ glaciation by 187Re/188Os dating of a Neoproterozoic post-glacial black shale in western Canada. Earth Planet Sci Lett 222:729-740
Kendall BS, Creaser RA, Selby D (2006) Re-Os geochronology of the post-glacial black shales in Australia: Constraints on the timing of “Sturtian” glaciation. Geology 34:729-732
Kerr AC (2005) Oceanic LIPs: The kiss of death. Elements 1:289-292
Klemme HD, Ulmishek GF (1990) Effective petroleum source rocks of the word: Stratigraphic distribution and controlling depositional factors. AAPG Bulletin 75(12):1809-1851
Ko T (2010) Characterization of gas generated by sequential hydrous pyrolysis of potential gas-prone source rocks for tight-gas reservoirs in the Rocky Mountain Area. MSc Thesis, Colorado School of Mines
Koopmans MP, Rijpstra WIC, Klapwijk MM et al (1999) A thermal and chemical degradation approach to decipher pristane and phytane precursors in sedimentary organic matter. Organic Geochemistry 30:1089-1104
Koopmans MP, Larter SR, Zhang C et al (2002) Biodegradation and mixing of crude oils in Eocene Es3 reservoirs of the Liaohe basin, northeastern china. AAPG Bulletin 86:1833-1843
Kreuzer RL, Darrah TH, Grove BS et al (2018) Structural and hydrogeological controls on hydrocarbon and brine migration into drinking water aquifers in Southern New York. Groundwater 56(2):225-244
Kribek B, Sykorova I, Machovic V et al (2008) Graphitization of organic matter and fluid-deposited graphite in Palaeoproterozoic (Birimian) black shales of the Kaya-Goren greenstone belt (Burkina Faso, West Africa). J. Metamorphic Geol. 26:937-958
Large DJ, Christy AG, Fallick AE (1994) Poorly crystalline carbonaceous matter in high grade metasediments: implications for graphitisation and metamorphic fluid compositions. Contrib Mineral Petrol 116:108-116
Larter S, Wilhelms A, Head I et al (2003) The controls on the composition of biodegraded oils in the deep subsurface - part 1: Biodegradation rates in petroleum reservoirs. Organic Geochemistry 34(4):601-613
Law CA (1999) Evaluating source rocks. In: AAPG Special Volumes. Volume Treatise of Petroleum Geology/Handbook of Petroleum Geology: Exploring for Oil and Gas Traps, 3.1-3.34
Lillis PG, Selby D (2013) Evaluation of the rhenium-osmium geochronometer in the Phosphoria petroleum system, Bighorn Basin of Wyoming and Montana, USA. Geochim Cosmochim Acta 118:312-330
Lijmbach GWM (1975) On the origin of petroleum. Proceedings of the Ninth World Petroleum Congress. Geology 2:357-369
Littke R, Lückge A, Wilkes H (1998) Organic matter in Neogene sediments of the Southern Canary Channel, Canary Island (Sites 955 and 956). In: Weaver PPE, Schminke H-U, Firth, JV, et al (eds), Proceedings of the ODP Scientific Results, 157:361-372
Liu J (2017) Re-Os Systematics of Crude Oil and Re-Os Petroleum System Geochronology. Durham Thesis, Durham University
Liu S, Qi S, Luo Z et al (2018a) The origin of high hydrocarbon groundwater in shallow Triassic aquifer in Northwest Guizhou, China. Environmental Geochemistry and Health 40(1):415-433
Liu J, Selby D, Obermajer M et al (2018b) Rhenium-osmium geochronology and oil-source correlation of the Duvernay petroleum system, Western Canada sedimentary basin: Implications for the application of the rhenium-osmium geochronometer to petroleum systems. AAPG Bulletin 102(8):1627-1657
Liu S, Qi S, Luo Z et al (2019) The origin of high hydrocarbon groundwater in shallow aquifer: Experimental evidences from water-rock interaction. Environmental Science and Pollution Research 26:32574-32588. https://doi.org/10.1007/s11356-019-06578-w
Ma JJ (2016) Geochemical Characterization of the Second White Speckled Shale Formation, Western Canada Sedimentary Basin and the Mass Fraction Maturity Defining Thermal Maturity Level. MSc Thesis, University of Calgary
Machel HG (1998) Gas souring by thermochemical sulfate reduction at 140°C: Discussion. AAPG Bulletin 82(10):1870-1873
Manzano BK, Fowler MG, Machel HG (1997) The influence of thermochemical sulphate reduction on hydrocarbon composition in Nisku reservoirs, Brazeau river area, Alberta, Canada. Organic Geochemistry 27(7/8):507-521
Marques JC (2012) Overview on the Re-Os isotopic method and its application on ore deposits and organic-rich rocks. Geochimica Brasiliensis Ouro Preto 26(1):49-66
Marzi R, Torkelson BE, Olson RK (1993) A revised carbon preference index. Organic Geochemistry 20(8):1303-1306
Massoud S, Al-Abdali F, Al-Ghadban AN et al (1996) Bottom sediments of the Arabian Gulf II: TPH and TOC contents as indicators of oil pollution and implications for the effect and fate of the Kuwait oil slick. Environmental Pollution 93(27):1-284
Matuszewska A (2002) Geochemıcal interpretatıon and comparison of biomarker composition of bitumens obtained from coals and surrounding rocks. Proceedings of the IV European Coal Conference, Polish Geological Institute Special Papers 7:169-180
McArthur JM, Algeo TJ, van de Schootbrugge B et al (2008) Basinal restriction, black shales, Re-Os dating, and the Early Toarcian (Jurassic) oceanic anoxic event. Paleoceanography 23(4):PA4217
Merchán-Rivera P (2017) Assessment of contamination by petroleum hydrocarbons from oil exploration and production activities in Aguarico, Ecuador. Study Project, Technical University of Munich, p 48
Mille G, Asia L, Guiliano M et al (2007) Hydrocarbons in coastal sediments from the Mediterranean Sea (Gulf of Fos area, France). Marine Pollution Bulletin 54:566-575
Ministry of Agriculture and Forestry of Turkey (2004a) Surface Water Quality Regulation of Turkey (in Turkish). Retrieved 02 June 2020 http://www.resmigazete.gov.tr/eskiler/2016/08/20160810-9.htm
Ministry of Agriculture and Forestry of Turkey (2004b) Water Pollution Control Regulation of Turkey (in Turkish). Retrieved 02 June 2020 http://www.mevzuat.gov.tr/Metin.Aspx?MevzuatKod=7.5.7221&MevzuatIliski=0&sourceXmlSearch=
Müller G (1979) Schwermetalle in den Sedimenten des RheinsVeãderung seit. Umschav 79:133-149
Murchison DG (1987) Recent advances in organic petrology and organic geochemistry: in overview with some references to “oil from coal”. In: Scott, A.C. (Ed.), Coal and Coal-bearing Strata: Recent Advances Geol Soc Special Publication 32:257-302
Nasir S, Fazeelat T (2013) Diamondoid hydrocarbons as maturity indicators for condensates from Southern Indus Basin, Pakistan. Journal of Chemistry. http://dx.doi.org/10.1155/2013/636845
Nwadinigwe CA, Alumona TN (2018) Assessment of n-alkanes and acyclic isoprenoids (geochemical markers) in crudes: A case study of Iraq and Niger delta, Nigeria. Egyptian Journal of Petroleum 27(1):111-116
Oforka NC, Osuji LC, Onojake MC (2012) Petroleum hydrocarbon fingerprinting of crude oils from Umutu/Bomu Oilfields in Niger Delta, Nigeria. Archives of Applied Science Research 4(1):246-253
Onojake MC, Osuji LC, Abrakasa S (2015) Source, depositional environment and maturity levels of some crude oils in southwest Niger Delta, Nigeria. Chin J Geochem 34(2):224-232
Orr WL (1974) Changes in sulfur content and isotopic ratios of sulphur during petroleum maturation: Study of Big Horn Basin Paleozoic oils. Part 1. AAPG Bulletin 58:2295-2318
Ozdemir A (2018) Usage of the Total Petroleum Hydrocarbons (TPH) in water analysis for oil and gas exploration: First important results from Turkey. Journal of Engineering Sciences and Design of Suleyman Demirel University 6(4):615-635 (in Turkish with English abstract)
Ozdemir A (2019a) Organic hydrogeochemical evidence of Hasanoğlan (Ankara) petroleum system. Pamukkale University Journal of Engineering Sciences 25(6):748-763 (in Turkish with English abstract)
Ozdemir A (2019b) Mature hydrocarbons-rich waters as geochemical evidence of working petroleum system of Mamak (Ankara) and potential trap area in the region. European Journal of Science and Technology 17:244-260 (in Turkish with English abstract)
Ozdemir A (2019c) Organic hydrogeochemical evidence of pre-Neogene petroleum system of the Buyuk Menderes graben and potential traps (Western Turkey). European Journal of Science and Technology 16:325-354 (in Turkish with English abstract)
Ozdemir A, Palabiyik Y (2019a) A new approach to petroleum source rock occurrence: The relationships between petroleum source rock, ophiolites, mantle plume and mass extinction. Paper presented at the IV. International scientific and vocational studies congress - engineering sciences (BILMES EN), Ankara, Turkey, 07 - 10 November 2019
Ozdemir A, Palabiyik Y (2019b) A shallow and reliable indicator for deep oil and gas accumulations in the subsurface: Metallic ore deposits. Paper presented at the IV. International scientific and vocational studies congress - engineering sciences (BILMES EN), Ankara, Turkey, 07 - 10 November 2019
Ozdemir A, Palabiyik Y (2019c) Significance of relationships between hydrocarbons and metallic ore deposits in oil and gas exploration: Part I. Gold deposits. Paper presented at BİLTEK International Symposium on Recent Developments in Science, Technology and Social Studies, Ankara, Turkey, 21-22 December 2019
Ozdemir A, Palabiyik Y (2019d) Significance of relationships between hydrocarbons and metallic ore deposits in oil and gas exploration: Part II. Copper deposits. Paper presented at BİLTEK International Symposium on Recent Developments in Science, Technology and Social Studies, Ankara, Turkey, 21-22 December 2019
Ozdemir A, Palabiyik Y (2019e) Significance of relationships between hydrocarbons and metallic ore deposits in oil and gas exploration: Part III. Lead and zinc deposits. Paper presented at BİLTEK International Symposium on Recent Developments in Science, Technology and Social Studies, Ankara, Turkey, 21-22 December 2019
Ozdemir A, Palabiyik Y (2019f) Use of Rhenium-Osmium (Re-Os) isotope for direct dating of organic-rich rocks and hydrocarbons/oils in petroleum geology: A review. Paper presented at ISPEC 4th International Conference on Engineering & Natural Sciences, Ankara, Turkey, 18-20 October 2019
Ozdemir A, Palabiyik Y (2019g) A review of Paleozoic - Miocene petroleum source rocks of Turkey by paleogeographic and paleotectonic data: New interpretations and major outcomes. Paper presented at the 7th International Symposium on Academic Studies in Science, Engineering and Architecture Sciences, Ankara, Turkey, 15-17 November 2019
Ozdemir A, Palabiyik Y (2020) Findings for Hydrocarbon Occurrence and Generation Associated with Possible Jurassic-Cretaceous Riftings in Eastern Pontides. Paper presented at the 4. International Academic Studies Conference, 28-30 September 2020 (in Turkish with English abstract)
Ozdemir A, Palabiyik Y (2022) A new method for geochemical prediction of the existence of petroleum reservoirs in magmatic and metamorphic rocks. In: Lin J. (eds) Proceedings of the 2021 International Petroleum and Petrochemical Technology Conference, IPPTC 2021, Springer, https://doi.org/10.1007/978-981-16-9427-1_64
Ozdemir A, Karataş A, Palabiyik Y et al (2020a) Oil and gas exploration in Seferihisar Uplift (Western Turkey) containing an operable-size gold deposit: Geochemical evidence for the presence of a working petroleum system. Geomechanics and Geophysics for Geo-Energy and Geo-Resources 6(30):1-22. https://doi.org/10.1007/s40948-020-00152-2
Ozdemir A, Palabiyik Y, Karataş A et al (2020b) Organic geochemical evidence of the working petroleum system in Beypazarı Neogene Basin and potential traps (Northwest Central Anatolia, Turkey). Turkish Journal of Geosciences 1(2):35-52
Ozdemir A, Karataş A, Palabiyik Y et al (2020c) Reservoir-targeted oil and gas exploration in the Karaburun Peninsula (Western Turkey). International Journal of Energy and Engineering Sciences 5(2):115-145
Ozdemir A., Sahinoglu, A., Palabiyik, Y. et al (2021) Reservoir-targeted oil and gas exploration in metamorphic and magmatic rocks of the Niğde Massif (Central Anatolia, Turkey). Journal of Scientific Reports-A 47: 1-26
Ozdemir A, Palabiyik Y, Karataş A et al (2022) Mature petroleum hydrocarbons contamination in surface and subsurface waters of Kızılırmak Graben (Central Anatolia, Turkey): Geochemical evidence for a working petroleum system associated with a possible salt diapir. Turkish Journal of Engineering 6(1):01-15
Palabiyik Y, Ozdemir A, Sahinoglu A et al (2020a) Evaluation of oil and gas potential of Uludağ Massif (Northwestern Anatolia) by a new geochemical method. Trakya University Journal of Engineering Sciences 21(1):45-66 (in Turkish with English abstract)
Palabiyik Y, Ozdemir A, Karataş A et al (2020b) Identification of Oil and Gas Potential of Kastamonu and Sinop Provinces and their Surroundings (Central Pontides) by Using Total Petroleum Hydrocarbons (TPH) in Water Analysis, İstanbul Technical University, Scientific Research Project ID: MAB-2019-42217 (Ongoing project)
Palabiyik Y, Ozdemir A (2019) Oil and gas seeps in Turkey: A review. Paper presented at the 7th International Symposium on Academic Studies in Science, Engineering and Architecture Sciences, Ankara, Turkey, 15-17 November 2019
Palabiyik Y, Ozdemir A (2020) Use of TPH (Total Petroleum Hydrocarbons) in water analysis for oil and gas exploration in Turkey: The case studies from Western, Northwestern, and Central Anatolia regions and major outcomes. Turkey IV Scientific and Technical Petroleum Congress, November 18-20, Ankara, Turkey (in press) (in Turkish)
Palacas JG, Anders DE, King JD (1984) South Florida Basin- A prime example of carbonate source rocks in petroleum, in J. G. Palacas, ed., Geochemistry and Source Rock Potential of Carbonate Rocks. AAPG Studies in Geology 18:71-96
Paul M, Reisberg L, Vigier N (2009) A new method for analysis of osmium isotopes and concentrations in surface and subsurface water samples. Chemical Geology 258:136-144
Peters KE (2000) Petroleum tricyclic terpanes: predicted physicochemical behavior from molecular mechanics calculations. Organic Geochemistry 31:497-507
Peters KE, Cassa MR (1994) Applied Source Rock Geochemistry. In: Magoon, LB, Dow WG (eds) The Petroleum System - from Source to Trap. AAPG Memoir 60, p 93-120
Peters KE, Fraser TH, Amris W et al (1999) Geochemistry of crude oils from eastern Indonesia. AAPG Bulletin 83:1927-1942
Peters KE, Fowler MG (2002) Applications of petroleum geochemistry to exploration and reservoir management. Organic Geochemistry 33:5-36
Peters KE, Walters CC, Moldowan JM (2005) The Biomarker Guide: Biomarkers and Isotopes in Petroleum Exploration and Earth History. Second Edn. Cambridge University Press, p 1155
Peters KE, Moldowan JM (1993) The Biomarker Guide, Interpreting Molecular Fossils in Petroleum and Ancient Sediments. Englewood Cliffs, Jersey, Prentice Hall, p 339-363
Petersen HI, Hertle M, Juhasz A et al (2016) Oil family typing, biodegradation and source rock affinity of liquid petroleum in the Danish North Sea. Journal of Petroleum Geology 39(3):247-268
Pletsch T, Appel J, Botor D et al (2010) Petroleum generation and migration. In: Doornenbal JC, Stevenson AG (eds.) Petroleum Geological Atlas of the Southern Permian Basin Area. EAGE Publications b.v. (Houten), p 225-253
Pierson-Wickmann AC, Reisberg L, France-Lanord C (2002) Behavior of Re and Os during low-temperature alteration: Results from Himalayan soils and altered black shales. Geochim Cosmochim Acta 66(9):1539-1548
Potter II RW, Harrington PA, Silliman AH et al (1996) Significance of geochemical anomalies in hydrocarbon exploration. In: Schumacher D, Abrams MA (eds.) Hydrocarbon migration and its near-surface expression. AAPG Memoir 66, p 431-439
Poturay VA, Kompanichenko VN (2019) Composition and distribution of saturated hydrocarbons in the thermal waters and vapor-water mixture of the Mutnovskii Geothermal Field and Uzon Caldera, Kamchatka. Geochemistry International 57(1):74-82
Prosser SA, Kornacki AS, Laughland M et al (2020) Identification and characterization of oil groups in the Midland Basin using geochemical source and maturity parameters measured on > 1,600 oils and condensates from 692 wells. Paper presented at Unconventional Resources Technology Conference, Austin, Texas, USA, 20-22 July 2020
Rantitsch G, Judik K (2009) Alpine metamorphism in the central segment of the Western Greywacke Zone (Eastern Alps). Geologica Carpathica 60(4):319-329
Rantitsch G, Grogger W, Teichert C et al (2004) Conversion of carbonaceous material to graphite within the Greywacke Zone of the Eastern Alps. Int J Earth Sci (Geol Rundsch) 93: 959-973
Ravizza G, Turekian KK (1989) Application of the 187Re-187Os system to black shale geochronometry. Geochim Cosmochim Acta 53:3257-3262
Ravizza G, Turekian KK, Hay BJ (1991) The geochemistry of rhenium and osmium in recent sediment from the Black Sea. Geochim Cosmochim Acta 55:3741-3752
Rice D (1993) Composition and Origins of Coalbed Gas. In: Law BE, Rice D (eds.) Hydrocarbons from Coal. AAPG Studies in Geology 38, p 159-184
Roadifer RE (1987) Size distributions of the world’s largest known oil and tar accumulations. In: Meyer RF (ed) Exploration for Heavy Crude Oil and Natural Bitumen. American Association of Petroleum Geologists, Tulsa, AAPG Studies in Geology 25, p 3-23
Rooney AD, Selby D, Houzay J-P et al (2010) Re-Os geochronology of a Mesoproterozoic sedimentary succession, Taoudeni basin, Mauritania: Implications for basin-wide correlations and Re-Os organic-rich sediments systematic. Earth Planet Sci Lett 289:486-496
Sahinoglu A, Ozdemir A, Palabiyik Y et al (2020a) Investigation of Oil and Gas Potential of Northern Ankara (Central Turkey) by Total Petroleum Hydrocarbons (TPH) in Water and Soil Analyses. İstanbul Esenyurt University, Scientific Research Project ID: BAP2019-02 (Ongoing project)
Sahinoglu A, Ozdemir A, Palabiyik Y et al (2020b) Investigation of Oil and Gas Potential of Ulukışla Basin (Central Turkey) by Total Petroleum Hydrocarbons (TPH) in Water and Soil Analyses. İstanbul Esenyurt University, Scientific Research Project ID: BAP2020-07 (Ongoing project)
Sainbayar A, Vosmerikov AV, Nordov E et al (2005) Study of individual hydrocarbons’ composition of gasoline fraction of Tamsagbulag oil, Mongolia. Journal of Petroleum Science and Engineering 46(4):233-242
Samoilenko VK, Shadrina ES, Goncharov IV et al (2019) The origin of hydrocarbon fluids and features of the formation of oil and gas fields in the Gydan Peninsula. Paper presented at the 29th International Meeting on Organic Geochemistry (IMOG). Gothenburg, Sweden, 1-6 September 2019
Sari GL, Trihadiningrum Y, Ni’matuzahroh N (2018) Petroleum hydrocarbon pollution in soil and surface water by public oil fields in Wonocolo Sub-district, Indonesia. Journal of Ecological Engineering 19(2):184-193
Sawicka N, Janeczek J, Fabiañska M et al (2018) Mineralogy and organic geochemistry of phyllite from the Dewon–Pokrzywna
deposit, the Opava Mountains (SW Poland). Geological Quarterly 62(4):817-828
Selby D, Creaser RA (2003) Re-Os geochronology of organic rich sediments: an evaluation of organic matter analysis methods. Chemical Geology 200:225-240
Selby D, Creaser RA (2005) Direct radiometric dating of the Devonian-Carboniferous timescale boundary using the Re-Os black shale geochronometer. Geology 33:545-548
Selby D, Mutterlose J, Condon DJ (2009) U-Pb and Re-Os Geochronology of the Aptian/Albian and Cenomanian/Turonian stage boundaries: Implications for timescale calibration, osmium isotope seawater composition and Re-Os systematics in organic-rich sediments. Chemical Geology 265:394-409
Shanmugam G (1985) Significance of coniferous rain forests and related oil. Gippsland Basin, Australia. AAPG Bulletin 69:1241-1254
Stein HJ, Hannah JL (2014) The emerging potential of Re‐Os isotope geochemistry for source rocks and maturation‐migration histories. Paper presented at International Petroleum Technology Conference (IPTC), Doha, Qatar, 20‐22 January 2014
Stein HJ, Hannah JL, Yang G et al (2014) Ordovician source rocks and Devonian oil expulsion on bolide impact at Siljan, Sweden - the Re‐Os story. Paper presented at International Petroleum Technology Conference (IPTC), Doha, Qatar, 20‐22 January 2014
Suárez-Ruiz I, Flores D, Filho JGM, et al (2012) Review and update of the applications of organic petrology: Part 1, geological applications. International Journal of Coal Geology 99(2012):54-112
Suchý V, Sandler A, Slobodník M et al (2015) Diagenesis to very low-grade metamorphism in lower Palaeozoic sediments: A case study from deep borehole Tobolka 1, the Barrandian Basin, Czech Republic. International Journal of Coal Geology 140:41-62
Suchý V, Sykorova I, Melka K et al (2007) Illite ‘crystallinity’, maturation of organic matter and microstructural development
associated with lowest-grade metamorphism of Neoproterozoic sediments in the Tepla´-Barrandian unit, Czech Republic. Clay Minerals 42:503-526
Sun YZ, Wang JX, Liu LF et al (2005) Maturity parameters of source rocks from the Baise Basin, South China. Energy Exploration and Exploitation 23(4):257-266
Sun YZ, Liu CY, Lin MY et al (2009) Geochemical evidences of natural gas migration and releasing in the Ordos Basin, China. Energy Exploration and Exploitation 27(1):1-13
Sun YZ, Qin SJ, Zhao CL et al (2010) Experimental study of early formation processes of macerals and sulfides. Energy and Fuels 24:1124-1128
ten Haven HL, Baas M, Kroot M et al (1987) Late Quaternary Mediterranean sapropels. III: assessment of source of input and palaeotemperature as derived from biological markers. Geochim Cosmochim Acta 51:803-810
Tissot B, Califet-Debyser Y, Deroo G et al (1971) Origin and evolution of hydrocarbons in early Toarcian shales, Paris Basin, France. AAPG Bulletin 55:2177-93
Tissot BP, Welte DH (1984) Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration. Springer-Verlag, p 699
Tran KL, Philippe B (1993) Oil and rock extract analysis. In: Bordenave ML (eds.) Applied Petroleum Geochemistry, p. 373-394
Tripathy GR, Hannah JL, Stein HJ et al (2014) Re‐Os age and depositional environment for black shales from the Cambrian‐Ordovician boundary, Green Point, western Newfoundland. Geochemistry, Geophysics, Geosystems 15:1021‐1037
Thompson JG (1982) Hydrocarbon source rock analyses of Pakawau Group and Kapuni Formation sediments, northwest Nelson and offshore South Taranaki, New Zealand. New Zealand Journal of Geology and Geophysics 25(2):141-148
Ulmishek GF, Klemme HD (1991) Depositional controls, distribution and effectiveness of world’s petroleum source rocks. US Geological Survey, p 59
US-EPA (US Environmental Protection Agency) (2009) Soil Hazard Categorization and Management. Industrial Waste Resource Guidelines (IWRG621). https://www.epa.vic.gov.au/about-epa/publications/iwrg621
Volk H (2020) Source Rocks, Bitumens and Petroleum Inclusions from the Prague Basin (Barrandian, Czech Republic) Constraints for Petroleum Generation and Migration from Petrology, Organic Geochemistry and Basin Modelling. PhD Thesis, RWTH Aachen University
Volkman JK, Alexander R, Kagi RI et al (1983) Demethylated hopanes in crude oils and their applications in petroleum geochemistry. Geochim Cosmochim Acta 47(4):785-794
Volkman JK, Maxwell JR (1986) Acyclic isoprenoids as biological markers. In: Johns RB (ed) Biological Markers in the Sedimentary Record, Elsevier, New York, p 1-42
Waples DA, Curiale JA (1999) Oil-Oil and Oil-Source Rock Correlations. In: Edward A, Foster D (eds.) Exploration for Oil and Gas Traps. AAPG, Chapter 8
Waples DW (1985) Geochemistry in Petroleum Exploration. International Human Resources Development Corp. p 232
Wardlaw GD, Nelson RK, Reddy CM et al (2011) Biodegradation preference for isomers of alkylated naphthalenes and benzothiophenes in marine sediment contaminated with crude oil. Organic Geochemistry 42:630-639
Wenger LM, Davis CL, Isaksen GH (2001) Multiple controls on petroleum biodegradation and impact on oil quality. SPE Reservoir Evaluation & Engineering 5:375-383
Winters JC, Williams JA (1969) Microbiological alteration of crude oil. I: The reservoir. Preprints. American Chemical Society Division of Fuel Chemistry, Paper PETR 86, p. E22–E31
Worden RH, Smalley PC, Oxtoby NH (1995) Gas souring by thermochemical sulfate reduction at 140 °C. AAPG Bulletin 79(6):854-863
Wright SC (2015) Applications of the Rhenium-Osmium Isotopic System, and Platinum and Iridium Abundances in Organic-Rich Mud Rocks: A Geochronology, Geochemistry, and Redox Study. PhD Thesis, University of Houston
Xia L, Cao L, Wang M et al (2019) A review of carbonates as hydrocarbon source rocks: basic geochemistry and oil-gas generation. Petroleum Science 16:713-728
Xu G, Hannah JL, Stein HJ et al (2014) Cause of Upper Triassic climate crisis revealed by Re‐Os geochemistry of Boreal black shales. Palaeogeography, Palaeoclimatology, Palaeoecology 395:222‐232
Xu G, Hannah JL, Stein HJ et al (2009) Re-Os geochronology of Arctic black shales to evaluate the Anisian-Ladinian boundary and global faunal correlations. Earth and Planetary Science Letters 288:581‐587
Xu G, Hannah JL, Stein HJ et al (2013) Application of Re‐Os geochemistry to sedimentary basins: stratigraphic correlation oil-source correlation and paleo‐environmental condition. First joint GSC‐GSA Meeting, Chengdu, Acta Geologica Sinica (English Edition) 87 (supplement): 602‐604
Yang ZH, Lien PJ, Huang WS et al (2015) Development of the risk assessment and management strategies for TPH-contaminated sites using TPH fraction methods. J Hazard Toxic Radioact Waste. https://doi.org/10.1061/(ASCE)HZ.2153-5515.0000290
Zamansani N, Rajabzadeh MA, Littke R et al (2019) Organic petrology and geochemistry of Triassic and Jurassic coals of the Tabas Basin, Northeastern/Central Iran. International Journal of Coal Science & Technology 6(3):354-371
Zdravkov A, Bechtel A, Sachsenhofer RF et al (2011) Vegetation differences and diagenetic changes between two Bulgarian lignite deposits - Insights from coal petrology and biomarker composition. Organic Geochemistry 42:237-254
Zemo DA, Foote GR (2003) The technical case eliminating the use of the TPH analysis in assessing and regulating dissolved petroleum hydrocarbons in groundwater. Groundwater Monitoring & Remediation 23(3):95-104
Zhou X, Jiao W, Han J et al (2010) Tracing hydrocarbons migration pathway in carbonate rock in Lunnan-Tahe oilfield. Energy Exploration & Exploitation 28(4):259-278
Published
2022-07-03
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