Geochemical Characterization of Soils in A Semi-Urban Extension Area of Minna, Northcentral Nigeria Using EDXRF Instrumental Analysis

Authors

  • Rafiu Jimoh Atanda Department of Water Resources and Agrometeorology,College of Environmental Resources Management,Federal university of agriculture abeokuta
  • Olubukola Ogungbade Department of Earth Science, Faculty of Science, Olabisi Onabanjo University, Ago Iwoye, Ogun State, Nigeria
  • Adeniji Moradeyo Department of Physical Sciences, School of Science, Yaba College of Technology, Lagos State, Nigeria
  • Okoli Ezindu Department of Civil Engineering, Federal Polytechnic, Oko, Anambra State, Nigeria
  • Oluwatobi Olaleye Department of Water Resources and Agrometeorology, Faculty of Agriculture, Federal University Oye Ekiti, Ekiti State, Nigeria
  • Jamiu Salami Department of Physics, School of Physical Sciences, Federal University of Technology,Minna,Niger State Nigeria

Keywords:

Pedogeochemistry, agrogeochemistry, white yam, minor, major, energy dispersive X-ray Fluorescence

Abstract

A study on pedogeochemistry and agrogeochemistry was conducted on an open Farm field to evaluate the trace and macro elements in the soil and their effects on Dioscorea rotundata (white yam) yield. Twenty soil samples were collected at predetermined depths and distances across the farm and analyzed using Energy Dispersive X-ray Fluorescence (EDXRF) focusing on soil geochemical anomalies and their impact on yam yield in Chanchaga Local Government Area, Niger State, Nigeria. Results showed that high potassium absorption led to impaired yield, harvest loss, and premature crop death. The mean concentrations of key elements were potassium (1.8%), calcium (1.5%), iron (1.4%), magnesium (0.42%), copper (127 ppm), zinc (127 ppm), and manganese (739 ppm), following the order K > Ca > Fe > Mg for minor elements and Mn > Zn for major elements. These values were compared with Alloway (1995) standards for essential nutrients in yam cultivation. Excessive potassium absorption negatively affects yam yield, while imbalanced element proportions can impact crop health and human consumption. Ensuring optimal soil geochemistry is crucial for sustainable yam production and food safety.

References

Abou El-Anwar, H.S., Mekky, W., Abdel Wahab, A.S., Asmoay, A.A., Elnazer Salman, S.A., 2019. Geochemical characteristics of agricultural soils, Assiut governorate, Egypt. Bulletin of the National Research Centre 43, 41 (2019). https://doi.org/10.1186/s42269-019-0080-3.

Adeola, A.A, Kelechi, L.N, Modupe, O.A, 2015.Assessment of Heavy Metals Pollution in Soils and Vegetation around Selected Industries in Lagos State, Nigeria. Journal of Geoscience and Environment Protection, 3, 11-19. http://dx.doi.org/10.4236/gep.2015.37002.

Adepoju, M.O., 2019. Geochemical Soil Survey for Base and Precious Metals in Dagbala-Atte District, Southwestern Nigeria. International Journal of Geosciences 10 (2), 141-159. http://dx.doi.org/10.4236/ijg.2019.102009.

Alloway, B.J, 1995. The essential elements, 2nd Edition.

Burke, M.G., Haigh, S.J., Lim, J.J., Janssen, A., 2015. Advanced Analytical Electron Microscopy: New Perspectives on Real Materials. Microscopy and Microanalysis 21 (3), 489-90.

Bzour, A.F., Hani, N.K., Sawsan, A.O., 2016. Assessment of bioavailability of Chromium (Cr), Vanadium (V) and Uranium (U) in plants in Siwaqa Area, Central Jordan. International Journal of Current Research in Biosciences and Plant Biology 3 (2), 48-94. http://dx.doi.org/10.20546/ijcrbp.2016.312.010.

Chand, P., Ruchi, S., Ramdeen, P., Rakesh, K.S., Yogesh, B.P., 2011. Determination of essential and toxic metals and its transversal pattern from soil to tea brew. Food and Nutrition Sciences 2, 1160-1165. http://dx.doi.org/10.4236/fns.2011.210155.

Edegbene, A.O., Elakhame, L.A., Arimoro, F.O., Osimen, E.C., Akamagwuna, F.C., Edegbene, O.T.T., 2023. Preliminary studies on macroinvertebrate biomonitoring of freshwater systems in the Afrotropics: a case study of the Chanchaga River in the Lower Niger-Benue Ecoregion of Nigeria. Biologia 78 (1), 1-14. https://doi.org/10.1007/s11756-023-01445-z.

Essiett, A.A., Bede, M.C., 2016. Elemental Analysis of Soil around Ikot Abasi L.G.A, Nigeria Using EDXRF. International Journal of Research 3 (9), 243-248. https://journals.pen2print.org/index.php/ijr/article/view/4416/4245.

Funtua, I.I., 2015. Application of the transmission-emission method in EDXRF for the determination of trace elements in geological and biological materials. Science Progress 98 (2), 121-138. https://doi.org/10.3184/003685015X14219955512794.

Grosheva, V., Zeichick, D., Zaichick, D., 2007. Application of INAA in the assessment of chemical elements in soils of the Khamar-Daban mountain range. Journal of Radio analytical and Nuclear Chemistry 271 (3), 565-572. https://doi.org/10.1007/s10967-007-0307-x.

Idris, Y., Funtua, II., Umar, I.M., 2004. Rapid Analysis with energy dispersive X-ray fluorescence spectrometry for bauxite investigation on the Mambilla Plateau, Northeastern Nigeria. Geochemistry 64 (4), 385-398. https://doi.org/10.1016/j.chemer.2003.10.002.

Idris-Nda, A., Abubakar, S.I., Waziri, S.H., Dadi, M.I., Jimada, A.M., 2015. Groundwater development in a mixed geological terrain: a case study of Niger State, central Nigeria.Water Resources Management,29 (15), 5479-5497. https://doi.org/10.2495/WRM1500711.

Ikoko, L.A.N., Briggs-Kamara, M.A., Sigalo, F.B., Ideriah, T.J., Ude, H.N., 2022. Elemental Composition Analysis of Soil Samples from Bayelsa State in the Niger Delta Region of Nigeria. Journal of Applied Sciences and Environmental Management 26 (4), 745-750. https://doi.org/10.4314/jasem.v26i4.26.

Kabata-Pendias, A., Pendias, H., 2001. Trace elements in soils and plants (3rd ed.). Boca Raton, FL: CRC Press.

Kihara, J., Bolo, P., Kinyua, M., Rurinda J., Piikki, K., 2020. Micronutrient deficiencies in African soils and the human nutritional nexus: opportunities with staple crops. Environmental Geochemistry and Health 42, 3015-3033. https://doi.org/10.1007/s10653-019-00499-w.

uLouise Fisher, Michael F. G, Aaron Baensch, Stephen J. B, James C and Guillaume D(2014). Resolution of geochemical and lithostratigraphic complexity: a workflow for application of portable X-ray fluorescence to mineral exploration. Geochemistry: Exploration, Environment, Analysis. http://dx.doi.org/10.1144/geochem2012-158.

Lu, H., Bian, R., Xia, X., Cheng, K., Liu, X., Liu, Y., Wang, P., Li, Z., Zheng, J., Zhang, X., Li, L., Joseph, S., Drosos, M., Pan, G., 2020. Legacy of soil health improvement with carbon increase following one time amendment of biochar in a paddy soil – A rice farm trial. Geoderma 376, 114567. https://doi.org/10.1016/j.geoderma.2020.114567.

Marguí. E, Queralt, I., Almeida, E., 2022. X-ray fluorescence spectrometry for environmental analysis: Basic principles, instrumentation, applications and recent trends. Chemosphere 303 (1), 135006. https://doi.org/10.1016/j.chemosphere.2022.135006.

Markl, G., Michael, A.W.M., Johannes, H., Thomas, W., 2014. Major, minor, and trace element composition of pyromorphite-group minerals as recorder of supergene weathering processes from the Schwarzwald mining district, SW Germany. American Mineralogist 99 (5-6), 1133-1146. http://dx.doi.org/10.2138/am.2014.4789.

Martinien, A., Letema, S., Schaab, G., Ngure, V., Mwesigye, A., Korir, N., 2023. Heavy metals and trace elements contamination risks in peri-urban agricultural soils in Nairobi city catchment, Kenya. Frontiers in Soil Science. https://doi.org/10.3389/fsoil.2022.1048057.

Muhammad, H., Abubakar, D.B., Salisu, A., Hussaini, A.D., 2019. Determination of Trace Elements Concentration in Soil Samples of Fika Agrarian Community of Yobe State, Nigeria, Using MP-AES Analytical Technique. The International Journal of Science and Technoledge 7 (12). https://doi.org/10.24940/theijst/2019/v7/i12/ST1910-024.

Njinga R.L., Moyo M.N., Abdulmaliq, S.Y., 2013. Analysis of Essential Elements for Plants Growth Using Instrumental Neutron Activation Analysis. International Journal of Agronomy Volume 2013, Article ID 156520, 9 pages. http://dx.doi.org/10.1155/2013/156520.

Papazotos, P., Liakopoulos, A., Kontodimos, K., Koukoulis, A., 2024. Integrated geochemical analysis of urban and peri-urban soils: a case study of Lamia City, Greece. Environmental Monitoring and Assessment 196, 1050. https://doi.org/10.1007/s10661-024-13223-8.

Riedel, T., Hennessy, P., Iden, S.C., Koschunsky, A., 2015. Leaching of soil derived major and trace elements in an arable top soil after the addition of biochar. European Journal of Soil Science 66 (4), 823-834. https://doi.org/10.1111/ejss.12256.

Roberts, D., Nachtegall, M., Sparks, D.L., 2005. Speciation of metals in soils. In M. A. Tabatabai, and D. L. Sparks (Eds.), Chemical processes in soils. Book Series No. 8, 19–654, Madison, WI: Soil Science Society of America.

Shackley, M.S., 2021. An energy-dispersive X-ray fluorescence analysis of major, minor, and trace elements of soil samples from Rio Verde, Oaxaca, West Mexico. University of California, eScholarship. https://escholarship.org/uc/item/18x2377v.

Smart, M.O., Fawole, O.A., Isola, J.O., Olatunji, O.A., 2017. Geochemical Assessment of Soils around Metal Recycling Industrial Areas in Ikorodu, Southwestern Nigeria. Global Journal of Science Frontier Research: H Environment and Earth Science 17 (2), 1.0 https://globaljournals.org/GJSFR_Volume17/5-Geochemical-Assessment-of-Soils.pdf.

Sudhakaran, M., Ramamoorthy, D., Savitha, V., Balamurugan, S., 2018. Assessment of trace elements and its influence on physico-chemical and biological properties in coastal agroecosystem soil Puducherry region. Geology, Ecology and Landslides 3 (2), 169-176. https://doi.org/10.1080/24749508.2018.1452475.

Thomas, A., Joachim, H., Dirk, W., 2016. In situ analysis of traces, minor and major elements in rocks and soils with a portable XRF Spectrometer, 12th Middle East Geosciences Conference & Exhibition, Manama, Bahrain, March 7-10. https://www.searchanddiscovery.com/documents/2016/41836thomas/ndx_thomas.pdf.

Towett, E.K., Keith, D.S., Jerome, E.T., Leigh, A.W., Tamene, L., Mercy, N., Andrew, S., Tor, G.V., 2015. Total elemental composition of soils in Sub Saharan Africa and relationship with soil forming factors. Geoderma Regional 5, 157-168. https://doi.org/10.1016/j.geodrs.2015.06.002.

Xiangdong, L., Thorton, I., 2001. Chemical partitioning of trace and major elements in soils contaminated by mining and smelting activities. Applied Geochemistry 16 (15), 1693-1703. https://doi.org/10.1016/S0883-2927(01)00065-8.

Zaher, B., Sameer, A., Basel, N., Mazen, S., 2012. Analysis of macro and micronutrients in soils from Palestine using Ion Exchange Membrane Technology. Journal of Soil Science 2, 44-49. https://doi.org/10.4236/ojss.2012.21007.

Downloads

Published

2025-08-31